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Neither Physics nor Chemistry: A History of Quantum Chemistry (Transformations: Studies in the History of Science and Technology)
Ebook Free Neither Physics nor Chemistry: A History of Quantum Chemistry (Transformations: Studies in the History of Science and Technology)
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Review
This is a first-rate book co-authored by the two leading experts in the history of quantum chemistry. They have achieved a detailed and complete interpretive synthesis which should stand for many years as the definitive book on the subject.―Mary Jo Nye, Horning Professor in the Humanities and Professor of History Emerita, Oregon State UniversityThis book by Gavroglu and Simões is a masterful investigation of the constitution of a new scientific discipline that is 'neither physics nor chemistry.' It is a book that cannot avoid becoming a standard work for a long time to come. It will be of great interest not only to historians and philosophers of science, but also to the large community of chemists.―Helge Kragh, Department of Science Studies, Aarhus University; author of Quantum GenerationsNeither Physics nor Chemistry is much more than a meticulously researched, authoritative history of quantum mechanical explanations of chemical structure. It is an insightful sociological and a commanding histriographical study of the formation of a modern new subdiscipline, quantum chemistry, and a searching examination of the impact that digital computers had on the field. It is also a highly instructive exploration of the consequences of these innovations for the culture of chemistry, and more generally for the philosophy of chemistry. It is a model for how to write the history of twentieth-century science, and Kostas Gavroglu and Ana Simões are to be commended for it.―S. S. Schweber, Koret Professor of the History of Ideas and Professor of Physics, Emeritus, Brandeis University
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About the Author
Kostas Gavroglu teaches in the Department of History and Science at the University of Athens.
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Product details
Series: Transformations: Studies in the History of Science and Technology
Hardcover: 368 pages
Publisher: The MIT Press (October 7, 2011)
Language: English
ISBN-10: 9780262016186
ISBN-13: 978-0262016186
ASIN: 0262016184
Product Dimensions:
7 x 1 x 9 inches
Shipping Weight: 1.7 pounds (View shipping rates and policies)
Average Customer Review:
4.0 out of 5 stars
1 customer review
Amazon Best Sellers Rank:
#2,347,411 in Books (See Top 100 in Books)
This book presents the first in-depth historical analysis of quantum chemistry, a field that according to the title is neither physics nor chemistry. I am not sure how many practicing quantum chemists will agree on this view point, nevertheless the authors provide compelling support for their thesis. Soon after the advent of quantum mechanics (QM) in 1925, Walter Heitler and Fritz London wrote a landmark paper where they expounded the first quantum mechanical treatment of the chemical bonding in the hydrogen molecule (H2). Soon after many talented physicists and chemists joined the field and two competing theories took shape: on the one side the valence bond (VB) theory of Heitler-London-Slater-Pauling and on the other the molecular orbital (MO) theory of Mulliken and Hund. Applied mathematicians (Coulson, Hartree, and later on Pople) also contributed greatly to this new field along with many other colleagues from Europe, US, and Japan. In 1967, the Swedish physicist Per-Olov Lowdin established the International Journal of Quantum Chemistry (IJQC) which represented an important step toward the consolidation of this scientific discipline.The authors, both professional historians of Science, explain in great detail all the intricacies connected with the theoretical formulation of the above VB and MO theories, starting from the pre-QM work of Gilbert Lewis on the electron pair concept that appeared in 1916 up to the early 1970s when computers (mainframes) became available to many research groups around the world. There are, however, some important details that they left out as practicing computational quantum chemists will notice. A notable name that is not mentioned inside the book is that of Kenichi Fukui, founder of the frontier molecular orbital (FMO) theory, who shared with Roald Hoffmann the 1981 Nobel Prize in Chemistry. FMO theory (published in The Journal of Chemical Physics in 1952) is a spin-off of MO theory and, given its success in the interpretation of chemical reactions it should have been included inside the book. The frontier orbitals HOMO (highest-occupied MO) and LUMO (Lowest-unoccupied MO) are often displayed inside research papers up to these days.Another important omission is that of density functional theory (DFT), which is now so popular among quantum chemists (the Kohn-Sham equations were given in a Phys. Rev. paper in 1965 - Walter Kohn shared with John Pople the Nobel Prize in Chemistry in 1998). Also, the VSEPR (valence-shell electron pair repulsion) theory of Gillespie, a spin-off of Lewis's electron pair theory, and the Ligand Field Theory (LFT) applied to inorganic complexes of transition metal ions are not mentioned throughout the book. Hence, I rated this book with four stars.In spite of the above omissions, however, the book of Gavroglu and Simoes is very worth reading and it is hoped that it will stimulate further historical studies on this important field of research which, in my opinion, is nowadays fully integrated into Chemistry (QC chairs are hosted almost everywhere at the Chemistry departments of Universities).Hereafter follows a short list of errata:1) p. 225 and 231: 1988 -> 1998 (year of the Nobel Prize in Chemistry to John Pople)2) p. 230: to who -> to whom3) p. 236 (Fig. 4.4): Elections -> Electrons4) p. 324 (title of Primas' book): Reduction -> Reductionism5) p. 341 (Index): Hoffman -> Hoffmann
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